The benzo‐fused N‐(pyrrolidinomethyl)pyrroles (I) and (VI) are selectively lithiated and then substituted with various electrophiles (II) to form the derivatives (III) or (VII) after deprotection.
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ChemInform Abstract: Improved Syntheses of Substituted Carbazoles and Benzocarbazoles via Lithiation of the (Dialkylamino)methyl (Aminal) Derivatives