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Chitosan as heterogeneous catalyst in Michael additions: the reaction of cinnamonitriles with active methylene moieties and phenols
Journal article   Open access  Peer reviewed

Chitosan as heterogeneous catalyst in Michael additions: the reaction of cinnamonitriles with active methylene moieties and phenols

Hamad M. Al-Matar, Khaled D. Khalil, Herbert Meier, Heinz Kolshorn and Mohamed H. Elnagdi
ARKIVOC free online journal of organic chemistry, Vol.2008(16), pp.288-301
01/01/2008

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
The reaction of active methylene moieties, pyrazolones, thiazolylacetonitriles, phenols and alkyl pyridazinones with benzylidene-malononitrile in ethanol in presence of chitosan afforded aminopyrancarbonitriles, pyranopyrazole, thiazolopyridines, chromenes, and pthalazines in yields comparable to those obtained in ethanolic piperidine. Much lower yields were obtained in aqueous solutions.
url
https://doi.org/10.3998/ark.5550190.0009.g27View
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