Abstract
The present study reports the successful functionalization/magnetization of bio-polymer to produce chitosan-magnetic graphene oxide grafted polyaniline doped with cobalt oxide (ChMGOP-Co3O4). Analytical techniques furrier transform infra-red (FT-IR), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDS) were used to confirm the formation of ChMGOP-Co3O4. The effects of several experimental factors (solution pH, adsorbent dosage and coexisting ions) on the uptake of As(V) ions using ChMGOP-Co3O4 were examined through batch experiments. As(V) removal process was validated by experimentally and theoretically investigating the adsorption capacity, rate, and thermal effects. Thermodynamic parameters such as free energy (ΔG°), entropy (ΔS°) and enthalpy (ΔH°) were also calculated and were used to explain the mechanism of adsorption. Based on the results, the sorbent showed a high adsorption capacities (90.91 mg/g) at favorable neutral pH and superior removal efficiencies as high as 89% within 50 min. In addition, the adsorption isotherm followed the Langmuir isotherm in compare to the Freundlich, due to its higher R2 value (0.992 < 0.941). Meanwhile, the kinetic data revealed that the of As(V) adsorption was controlled by pseudo-second-order. Overall, the adsorption mechanism studies revealed a spontaneous endothermic nature with predominance of physisorption over chemisorption. This study indicated that ChMGOP-Co3O4 is an exceptional novel adsorbent material for the efficient isolation of As(V) from aqueous media.
•Bio-polymer of chitosan-polyaniline over magnetic graphene oxide and cobalt oxide developed.•Uptake of As(V) ions using ChMGOP-Co3O4 is obtained as high as 89% within 50 min.•Adsorbent showed a high sorption capacity (90.91 mg g-1) for As(V) at favorable pH.•Adsorption process followed the Langmuir isotherm due to high value of R2 (0.992).•Kinetic revealed that the adsorption process was controlled by pseudo-second-order