The first reactions of the trinuclear oxygen-centred iron carboxylate [Fe-3(mu(3)-O)(mu(2)-piv)(6)(H2O)(3)](piv) (piv = (BuCOO-)-Bu-t) with the neutral ligand precursor [RP(S)(mu-S)](2) (R = 4-anisyl) are reported.
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Title
Cleavage of P-S bonds and oxygenation by a trinuclear iron carboxylate: Synthesis and structures of iron clusters containing group 15/16 anions
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Tatiana V. Mitkina - Karlsruhe Institute of Technology
Yanhua Lan - Karlsruhe Institute of Technology
Valeriu Mereacre - Karlsruhe Institute of Technology