Abstract
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► Co–Zn ferrite nanoparticles were produced by soft chemistry. ► Cation distribution deviation from the thermodynamically stable one was evidenced. ► The magnetic characteristics were affected and differ from those of bulks.
Highly crystalline stoichiometric Co1−xZnxFe2O4 (0≤x≤1) nanoparticles were successfully synthesized by the polyol process. X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), transmission electron microscopy (TEM), infrared spectroscopy (IR), zero-field 57Fe Mössbauer spectrometry and magnetic measurements using a SQUID magnetometer were employed to investigate the effect of the substitution of Zn2+ ions for Co2+ ones on the structure, and the magnetic properties of the cobalt ferrite, CoFe2O4. The unit cell parameter almost increases linearly with increasing Zn concentration, x, following Vegard's law. The red and blue shifts observed for the metal-oxygen ν1 and ν2IR vibration bands, respectively, were consistent with the preferential entrance of Zn2+ ions in tetrahedral sites. Besides, detailed magnetic investigation in correlation with the cation distribution has been reported. All the particles exhibit superparamagnetic behaviour at room temperature. In addition, the magnetic characteristics (blocking temperature, saturation magnetization, coercivity, Curie temperature) clearly depend on the chemical composition and cation distribution. Both the blocking temperature and Curie temperature decrease drastically with Zn composition, x, increase. Further, the saturation magnetization follows an almost bulk-like behaviour with values notably larger than that of the bulk, mainly attributed to cation distribution deviation.