Abstract
Several years have passed since the global phase-out of leaded petrol use. Nonetheless, emissions from anthropogenic activities remain the principal source of Pb to the oceans. The distribution of elemental Pb and its stable isotopes throughout the surface ocean provide information on the source and transport of these anthropogenic inputs. This study presents dissolved Pb concentrations and isotopic distributions from 110 surface water samples collected during the Malaspina 2010 Circumnavigation Expedition. Dissolved Pb concentrations ranged from 10 pM to 49 pM across the sampling stations covering all major ocean basins. The highest concentrations were found in the northeast Atlantic Ocean and the lowest in both the south Pacific and south Atlantic Oceans. Lead concentrations measured in the north Pacific Ocean, near Hawaii, were compared to previously published data from the same region. That comparison showed that Pb concentration has decreased similar to 40% since 1975, although the rate of decrease has slowed in the past two decades. The overall decline in concentration probably has been induced by the cessation of leaded gasoline use in North America. The temporal evolution of stable Pb isotopes in this region shows a shift from dominant North American-like composition in 1979 towards a more Asian-like composition in later years. More widely, the distribution of Pb and Pb isotopes measured in the Malaspina sample set of global surface waters were compared with previously published ratios of aerosols and other atmosphere-derived Pb sources from the countries surrounding the different ocean basins. This comparison identified the potential Pb sources to each ocean basin, providing new insights into the transport and fate of Pb in the oceans. (C) 2018 Elsevier Ltd. All rights reserved.