Conjugatged Oligomeric Coordinated Silver Phenylacetylide Derivatives With Ultrafast Optical Kerr Effect

Y. H. Xu; B.K. Teo; H.M. Wu; S.L. Guo; Y.K. He; H.Y. Chen; W. Qian; S.J. Wu; Y.H. Zuo

doi:10.1557/PROC-665-C8.5

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Journal article

Conjugatged Oligomeric Coordinated Silver Phenylacetylide Derivatives With Ultrafast Optical Kerr Effect

Y. H. Xu, B.K. Teo, H.M. Wu, S.L. Guo, Y.K. He, H.Y. Chen, W. Qian, S.J. Wu and Y.H. Zuo

MRS proceedings, Vol.665, pp.295-300

2001

DOI: https://doi.org/10.1557/PROC-665-C8.5

Abstract

Silver phenylacetylide prepared by one-step process was characterized as a linear coordinated polymeric compound by matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) mass spectroscopy. Its prominent third-order optical nonlinearity was detected by heterodyned ultrafast optical Kerr effect (OHD-OKE) measurement. The second-order hyperpolarizability was enhanced by 2 orders of magnitude by means of incorporation of proper electron-pushing groups. The structure status was further investigated by quantum chemical calculation and molecular modeling.

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Title: Conjugatged Oligomeric Coordinated Silver Phenylacetylide Derivatives With Ultrafast Optical Kerr Effect
Creators - without role: Y. H. Xu - University of Illinois at Chicago
B.K. Teo - University of Illinois at Chicago
H.M. Wu - Peking University
S.L. Guo - Peking University
Y.K. He - Peking University
H.Y. Chen - Peking University
W. Qian - Peking University
S.J. Wu - Peking University
Y.H. Zuo - Peking University
Contributors - without role: G.E. Jabbour
B. Meijer
N.S. Sariciftci
T.M. Swager
Publication Details: MRS proceedings, Vol.665, pp.295-300
Publisher: Cambridge University Press
Number of pages: 6
Identifiers: 9941645008331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article