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Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis
Journal article   Open access  Peer reviewed

Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

Sumit Sachdeva, Alexey Pustovarenko, Ernst J. R. Sudholter, Freek Kapteijn, Louis C. P. M. de Smet and Jorge Gascon
CrystEngComm, Vol.18(22), pp.4018-4022
01/01/2016
DOI: https://doi.org/10.1039/c5ce02462e

Abstract

Chemistry Chemistry, Multidisciplinary Crystallography Physical Sciences Science & Technology
A study of a copper-based metal-organic framework (MOF) synthesized by an electrochemical route is presented. Morphological and adsorption properties of the MOF synthesized as bulk powder and on supported copper surfaces were investigated. Differences in these properties and structural refinement studies indicate that when 4,4',4 ''-s-triazine-2,4,6-triyl-tribenzoic acid (H(3)TATB) is used as linker interpenetration can be prevented when the structure is grown on a surface.
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