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Copper-catalyzed trifluoromethylation of arylsulfinate salts using an electrophilic trifluoromethylation reagent
Journal article   Peer reviewed

Copper-catalyzed trifluoromethylation of arylsulfinate salts using an electrophilic trifluoromethylation reagent

Xiaoxi Lin, Guimei Wang, Huaifeng Li, Yuanyuan Huang, Weiming He, Dandan Ye, Kuo-Wei Huang, Yaofeng Yuan and Zhiqiang Weng
Tetrahedron, Vol.69(12), pp.2628-2632
25/03/2013
DOI: https://doi.org/10.1016/j.tet.2013.01.041

Abstract

Aryltrifluoromethylsulphones Copper catalyst Electrophilic trifluoromethylation reaction
A copper-catalyzed method for the trifluoromethylation of arylsulfinates with Togni's reagent has been developed, affording aryltrifluoromethylsulfones in moderate to good yields. A wide range of functional groups in arylsulfinates are compatible with the reaction conditions. [Display omitted]

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