The synthesis of [(PhAs)2(micro-S2)(micro-S)] and its reactions to form novel Cu(I) complexes are reported, together with a new cleavage reaction of disulfides by Cu(I) thiolates and tertiary phosphines.
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Title
Copper-mediated cleavage of disulfides by tertiary phosphines: a new route to As-S anions
Creators - without role
Robert Langer - Karlsruhe Institute of Technology
Weifeng Shi
Alexander Rothenberger - Karlsruhe Institute of Technology
Publication Details
Dalton transactions : an international journal of inorganic chemistry, (37), pp.4435-4437