Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

Maria Daoudi; Najib Ben Larbi; Driss Benjelloun; Abdelali Kerbal; Jean Pierre Launay; Jacques Bonvoisin; Joël Jaud; Mostafa Mimouni; Taibi Ben-Hadda

doi:10.3390/70900690

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Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

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Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

Maria Daoudi, Najib Ben Larbi, Driss Benjelloun, Abdelali Kerbal, Jean Pierre Launay, Jacques Bonvoisin, Joël Jaud, Mostafa Mimouni and Taibi Ben-Hadda

Molecules (Basel, Switzerland), Vol.7(9), pp.690-696

01/09/2002

DOI: https://doi.org/10.3390/70900690

PMCID: PMC6146541

Abstract

flexible ligand

pyrazole

Structure

tridentate

tripod

The tripodal ligand N,N-bis-(3-carbomethoxy-5-methylpyrazol-1-yl)methyl aniline ( 2 ) has been prepared by the condensation of aniline with two equivalents of N-hydroxymethyl[3-carbomethoxy-5-methyl]pyrazole. The molecule consists of two structurally analogous 3-carbomethoxy-5-methylpyrazol-1-ylmethyl moieties, which adopt a transoidal conformation via a central aniline ring, suggesting that this tripodal ligand is highly flexible and could accommodate many metals by coordination.

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Title: Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline
Creators - without role: Maria Daoudi - 1 Département de Chimie, Faculté des Sciences, Dhar El Mehraz, 50000 Fés, Morocco
Najib Ben Larbi - Département de Chimie, Faculté des Sciences, Dhar El Mehraz, 50000 Fés, Morocco CEMES, CNRS, 29, rue Jeanne Marvig, 31055 Toulouse Cedex 04, France Département de Chimie, Faculté des Sciences, 60000 Oujda, Morocco
Driss Benjelloun - Département de Chimie, Faculté des Sciences, Dhar El Mehraz, 50000 Fés, Morocco CEMES, CNRS, 29, rue Jeanne Marvig, 31055 Toulouse Cedex 04, France Département de Chimie, Faculté des Sciences, 60000 Oujda, Morocco
Abdelali Kerbal - Département de Chimie, Faculté des Sciences, Dhar El Mehraz, 50000 Fés, Morocco CEMES, CNRS, 29, rue Jeanne Marvig, 31055 Toulouse Cedex 04, France Département de Chimie, Faculté des Sciences, 60000 Oujda, Morocco
Jean Pierre Launay - Centre d’Élaboration de Matériaux et d’Études Structurales
Jacques Bonvoisin - Département de Chimie, Faculté des Sciences, Dhar El Mehraz, 50000 Fés, Morocco CEMES, CNRS, 29, rue Jeanne Marvig, 31055 Toulouse Cedex 04, France Département de Chimie, Faculté des Sciences, 60000 Oujda, Morocco
Joël Jaud - Département de Chimie, Faculté des Sciences, Dhar El Mehraz, 50000 Fés, Morocco CEMES, CNRS, 29, rue Jeanne Marvig, 31055 Toulouse Cedex 04, France Département de Chimie, Faculté des Sciences, 60000 Oujda, Morocco
Mostafa Mimouni - 3 Département de Chimie, Faculté des Sciences, 60000 Oujda, Morocco
Taibi Ben-Hadda - Département de Chimie, Faculté des Sciences, Dhar El Mehraz, 50000 Fés, Morocco CEMES, CNRS, 29, rue Jeanne Marvig, 31055 Toulouse Cedex 04, France Département de Chimie, Faculté des Sciences, 60000 Oujda, Morocco
Publication Details: Molecules (Basel, Switzerland), Vol.7(9), pp.690-696
Publisher: MDPI
Identifiers: 9931365508331
Academic Unit: Umm Al Qura University
Language: English
Resource Type: Journal article