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Crystal structure of Na4Li4(saccharinate)(8)center dot 14H(2)O and its comparison with other alkali metal saccharinates
Journal article   Peer reviewed

Crystal structure of Na4Li4(saccharinate)(8)center dot 14H(2)O and its comparison with other alkali metal saccharinates

Prashant M. Bhatt and Gautam R. Desiraju
Journal of molecular structure, Vol.871(1-3), pp.73-79
15/12/2007
DOI: https://doi.org/10.1016/j.molstruc.2007.01.063

Abstract

Chemistry Chemistry, Physical Physical Sciences Science & Technology
Na4Li4(sac)(8)center dot 14H(2)O was prepared by co-crystallisation of equimolar amounts of LiCl and Na-saccharinate from water. The asymmetric unit contains 4 Na+ ions, 4 Li+ ions, 8 sac anions and 14 water molecules. The present structure bears some structural similarities to the already reported structure of the "dihydrate" Na-16(sac)(16)center dot 30H(2)O, and to Li-6(sac)(16)center dot 30H(2)O, and helps in understanding these structures better. (c) 2007 Elsevier B.V. All rights reserved.

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