Crystallographic evidence for intermolecular hydrogen bonding between aryl groups and OH groups in silanols

Salih S. Al-Juaid; Ahmad K.A. Al-Nasr; Colin Eaborn; Peter B. Hitchcock

doi:10.1016/0022-328X(92)83258-J

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Crystallographic evidence for intermolecular hydrogen bonding between aryl groups and OH groups in silanols

Journal article

Peer reviewed

Crystallographic evidence for intermolecular hydrogen bonding between aryl groups and OH groups in silanols

Salih S. Al-Juaid, Ahmad K.A. Al-Nasr, Colin Eaborn and Peter B. Hitchcock

Journal of organometallic chemistry, Vol.429(2), pp.C9-C13

19/05/1992

DOI: https://doi.org/10.1016/0022-328X(92)83258-J

Abstract

In crystals of the silanols (Me 3Si) 3CSiPh(X)OH (X  I or OMe) there is intermolecular π ⋯ HO bonding between a phenyl group in one molecule and an OH group in another, and there are probably intramolecular π ⋯ HO interactions in two silanols previously reported to show no hydrogen bonding. It is suggested that similar interactions should exist for OH groups attached to other metals or metalloids.

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Title: Crystallographic evidence for intermolecular hydrogen bonding between aryl groups and OH groups in silanols
Creators - without role: Salih S. Al-Juaid - University of Sussex
Ahmad K.A. Al-Nasr - University of Sussex
Colin Eaborn - University of Sussex
Peter B. Hitchcock - University of Sussex
Publication Details: Journal of organometallic chemistry, Vol.429(2), pp.C9-C13
Publisher: Elsevier B.V
Identifiers: 9936076808331
Academic Unit: King Abdulaziz University
Language: English
Resource Type: Journal article