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Cu(I) catalyzed synthesis of anhydrides from aldehydes via CDC-pathway at ambient temperature
Journal article   Peer reviewed

Cu(I) catalyzed synthesis of anhydrides from aldehydes via CDC-pathway at ambient temperature

Yasin Nuree, Raju Singha, Munmun Ghosh, Pronay Roy and Jayanta K. Ray
Tetrahedron letters, Vol.57(13), pp.1479-1482
30/03/2016
DOI: https://doi.org/10.1016/j.tetlet.2016.02.066

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
A one-pot simple and concise methodology has been developed for synthesizing aromatic carboxylic anhydrides starting from easily accessible aromatic aldehydes using cuprous chloride as the catalyst and TBHP as the oxidant in DMSO solvent to garner moderate to good yields via radical pathway in short and convenient reaction time at room temperature. (C) 2016 Elsevier Ltd. All rights reserved.

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