Abstract
Imines 1a-e derived from benzaldehyde or 3,4-dimethoxy benzaldehyde and ether- or alcohol-functionalised amines H2NR (R = C2H4OMe, C3H6OMe, C2H4OH, C3H6OH,) all undergo cyclometallation with [ Pd(OAc)(2)](3) (in some cases the dimeric products 2 were isolated) and subsequently react with lithium chloride to give chloride complexes, which are dimeric 3a-c, or monomeric for the C3H6OH-functionalised complexes 4d,e which have a C, N, O tridentate imine. The chloride complexes subsequently react with triphenylphosphine, and in some cases pyridine, to give mononuclear complexes 5 and 6, respectively with bidentate C, N imines. Treatment of 5 with silver salts leads to cations, the length of the tether (C2 or C3) and nature of the donor (ether or alcohol) and the counterion all effect whether or not the oxygen is coordinated. (C) 2007 Elsevier B.V. All rights reserved.