Sign in
Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis
Journal article   Peer reviewed

Dehydrogenative Aromatization and Sulfonylation of Pyrrolidines: Orthogonal Reactivity in Photoredox Catalysis

Angewandte Chemie (International ed.), Vol.57(45), pp.14787-14791
05/11/2018
PMID: 30307106

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Oxidative dehydrogenative aromatization and selective sulfonylation reactions of N-heterocycles under visible-light photoredox catalysis were established. The mild reaction conditions make this approach an appealing and versatile strategy to functionalize/oxidize pyrrolidines whereby arylsulfonyl chlorides were identified to be both catalyst regeneration and sulfonylation reagents.

Metrics

1 Record Views

Details