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Design of New Amino Tf-Amide Organocatalysts: Environmentally Benign Approach to Asymmetric Aldol Synthesis
Journal article   Open access  Peer reviewed

Design of New Amino Tf-Amide Organocatalysts: Environmentally Benign Approach to Asymmetric Aldol Synthesis

Hyo-Jun Lee, Natarajan Arumugam, Abdulrahman I. Almansour, Raju Suresh Kumar and Keiji Maruoka
Synlett, Vol.30(4), pp.401-404
01/03/2019
DOI: https://doi.org/10.1055/s-0037-1610408

Abstract

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Abstract A new type of optically pure primary amino aromatic Tf-amide organocatalyst can be easily prepared from 8-amino-1-tetralone, and its chemical behavior was investigated in the context of asymmetric aldol and Mannich reactions. Most notably, the asymmetric aldol reaction proceeded smoothly in brine.
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https://doi.org/10.1055/s-0037-1610408View
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