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Diamidonaphthalene-supported pnictogenium cations: Synthesis of an N-heterocyclic stibenium cation by a novel protonation route
Journal article   Peer reviewed

Diamidonaphthalene-supported pnictogenium cations: Synthesis of an N-heterocyclic stibenium cation by a novel protonation route

Heather A. Spinney, Ilia Korobkov and Darrin S. Richeson
Chemical communications (Cambridge, England), (16), pp.1647-1649
28/04/2007
DOI: https://doi.org/10.1039/b617434e
PMID: 17530088

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
A 1,8-bis(alkylamido)naphthalene framework has been applied to the construction of N-heterocyclic arsenium and stibenium cations; a novel synthetic route, involving protonation of an ancillary amido ligand, was used to generate the base-stabilized stibenium cation.

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