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Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid
Journal article   Peer reviewed

Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid

Stephan Bernt, Vincent Guillerm, Christian Serre and Norbert Stock
Chemical communications (Cambridge, England), Vol.47(10), pp.2838-2840
01/01/2011
DOI: https://doi.org/10.1039/c0cc04526h
PMID: 21253627

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
For the first time, functionality has been covalently introduced into the Cr-MIL-101 network by post-synthetic modification of the terephthalate linker molecule through nitration. The nitro group was reduced and the amino group was reacted with ethyl isocyanate to yield the corresponding urea derivative.

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