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Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species
Journal article   Peer reviewed

Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species

E. Callens, E. Abou-Hamad, N. Riache and J. M. Basset
Chemical communications (Cambridge, England), Vol.50(30), pp.3982-3985
18/04/2014
PMID: 24609531

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Extensive solid-state NMR analyses unambiguously determine the formation of silica supported W bis-methylidene methyl species by reaction of the corresponding methyl carbyne with trimethylphosphine or a cyclic olefin.

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