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Diverse catalytic reactivity of a dearomatized (PNP)-P-3-nickel hydride pincer complex towards CO2 reduction
Journal article   Peer reviewed

Diverse catalytic reactivity of a dearomatized (PNP)-P-3-nickel hydride pincer complex towards CO2 reduction

Huaifeng Li, Theo P. Goncalves, Qianyi Zhao, Dirong Gong, Zhiping Lai, Zhixiang Wang, Junrong Zheng and Kuo-Wei Huang
Chemical communications (Cambridge, England), Vol.54(81), pp.11395-11398
18/10/2018
DOI: https://doi.org/10.1039/c8cc05948a
PMID: 30175825

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
A dearomatized (PNP)-P-3*-nickel hydride complex has been prepared using an oxidative addition process. The first nickel-catalyzed hydrosilylation of CO2 to methanol has been achieved, with unprecedented turnover numbers. Selective methylation and formylation of amines with CO2 were demonstrated by such a (PNP)-P-3*-nickel hydride complex, highlighting its versatile functions in CO2 reduction.

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