Abstract
Runoff from agricultural irrigation is contaminated and loaded with pesticides. Frequent toxic levels of pesticide detection in the ecosystem motivate scientists and engineers to diminish agro-chemicals flowing into the environment. Constructed wetland, CWs, treatments are a sustainable methodology of special interest since it possess a symbiosis value. Flytek (FT) pesticide use has increased at an unprecedented rate for crop production as well as an increase in runoff loaded with Flytek. This study introduces the use of constructed wetlands based on an alum- sludge substrate for the purpose of Flytek (FT) removal performance. The system is based on an adsorption column and a sludge cake coupled with gravel acting as a carrier in order to be an adsorption bed and filtration system for Flytek removal. The structure, morphology and characteristics of the adsorption bed material "alum sludge" were characterized using X-ray diffraction spectroscopy and Scanning Electron Microscope (SEM). Additionally, Fourier-Transform infrared spectroscopy (FTIR) was explored. The experimental results revealed that a vertical flow constructed wetland is significant in eliminating the Flytek pesticide. However, the amount and height of sludge in a wetlands column affects its removal efficiency with the optimal removal (96%) being linked to the presence of sludge in 80%. Moreover, temperature, pH and the FT load showed a significant effect in removals, with the optimal operating conditions being recorded at 7.2 pH, 26 degrees C and 100 ppm of FT. The kinetic modeling is also investigated to validate the practical life applications and designs, and the results verified the reaction follows the pseudo 2nd-order reaction kinetic model according to the correlation coefficient factor. Furthermore, according to the isotherm model results the scheme follows the Freundlich isotherm model. Such preliminarily data of a gravel-alum-sludge-adsorption-column scheme is a good indicator in developing a constructed wetland facility being a good candidate for controlling agriculture effluent streams.