Abstract
Mechanical properties of toughened epoxy resin with two nano particles sizes of TiO
2 (17
nm and 50
nm) at different weight fractions (1%, 3%, 5% and 10%) were investigated and compared to that of submicron particles at 220
nm. The composites were characterized by tensile, flexural, pull-off and abrasion tests, followed by X-ray photoelectron spectroscopy and scanning electron microscopy of the fracture surfaces. The investigated epoxy depicted high performance epoxy systems formulated with low molecular weight epoxy resin and diethyltoluenediamine as a curing agent.
Results indicate an enhancement in the epoxy composite mechanical properties due to the addition of small fraction of TiO
2 particles. Highest tensile stress values were found at 3
wt.% for 17
nm and 50
nm particles and at 5
wt.% for 220
nm particles. The maximum flexural properties were found at lower TiO
2 fraction of 1
wt.% only. The flexural behavior of the epoxy composite was not improved by further addition of the filler. The enhancement of modified epoxy with the smaller nano particles size showed a better resistance to weight loss. It is suggested that the amount of particles present and its size affect the matrix deformation and as a result, the quality of interface in the composite. A relation between tensile and flexural stress as function of the toughened particle size was found.