Abstract
Silicon carbide (SiC) is a technologically significant material. A recent report on the abundance of C(60)fullerenes in interstellar space, along with the presence of SiC precursors, sparked interest in potentially similar SiC nanostructures. C(60)fullerene was found experimentally and is an exceptionally stable form of carbon. As Si and C have similar valence electron properties, it has been long envisioned that Si and SiC could also form similar fullerene-type structures. In this paper, Si(30)C(30)fullerene-derived clusters were studied from the first principle, starting from an ideal Si(60)fullerene template with various arrangements of silicon and carbon atoms and then relaxing them without any symmetry constraint. Hydrogen passivation was considered as well to model the effect of ligands that may be available during chemical synthesis processes. We have found that, after passivation, the relative stability of different configurations of Si(30)C(30)clusters changed compared to the unpassivated structures, while some structures collapsed. We have also noticed several Si-Si and Si-C double bonds in the unpassivated structures. Upon relaxation, some Si atoms lost their hydrogen, while carbon atoms capture those hydrogen atoms. Finally, we tested the endohedral doping of a transition metal, tungsten atom, to stabilize and magnetize Si30C30. With hydrogen passivation, the magnetic moment on W atom was enhanced. Overall, the effects of passivation on these fullerene structures are not very straightforward.