Sign in
Back
Efficient Stereoselective Glycosylations of Alcohols by Sugar Perpivalates: The First Use of 1-O-Pivaloylated Glycosyl Donors
Journal article   Peer reviewed

Efficient Stereoselective Glycosylations of Alcohols by Sugar Perpivalates: The First Use of 1-O-Pivaloylated Glycosyl Donors

Aliaksei V. Pukin and Han Zuilhof
Synlett, Vol.2009(20), pp.3267-3270
2009
DOI: https://doi.org/10.1055/s-0029-1218361

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
1-O-Pivaloyl glycosides were shown to be efficient glycosyl donors by using the perpivaloylated derivatives of lactose, galactose and glucose in the direct ZnCl2-promoted glycosylations of various alcohols. The corresponding glycosides were isolated in good yields and beta-selectivity.

Metrics

1 Record Views

Details