Abstract
Vegetable oils derived from rapeseed and its genetic variant canola, are conventionally extracted from oilseeds by means of an organic solvent, typically hexane. Concerns regarding the toxicity of hexane have meant safer and more environmentally friendly solvents such as terpenes are becoming attractive. In this research, the degumming of canola oil/terpene mixtures using ultrafiltration is considered as a critical step in such an extraction process. Polysulfone (PSF) and polyethersulfone (PES) membranes were found to be ineffective in this application, as the oil appeared to cause swelling of the membrane structure. This meant that the original flux could not be restored after cleaning. Conversely, a ceramic membrane (MWCO 5 kDa) provided stable behaviour over several cycles of operation when cleaned with pure solvent at high cross-flow velocity at 40 °C. This membrane showed high phospholipid retention (95 ± 2%), although some oil was also retained (16 ± 3%). Cymene emerged as the most attractive of the three terpenes tested, with higher permeate flux and phospholipid rejection than limonene or pinene.
While hexane has been traditionally used for oilseed extraction, toxicity concerns are likely to restrict its industrial use in the future. This article provides information to engineers and food scientists on the use of terpenes as an alternative solvent. In particular, the potential for ultrafiltration to be used in degumming of canola oil/terpene mixture is assessed. Our research shows that polymeric membranes are unlikely to be useful at scale in this application, as they are not readily cleaned for reuse. Conversely, a ceramic membrane of 5 kDa pore size provides the necessary rejection of phospholipids. There is some oil retention, that might require a downstream recovery step. The best results were obtained with cymene, suggesting this is a good target for industrial use.
•Ultrafiltration used for degumming of canola oil in terpene solvents.•Polymeric membranes swelled significantly and could not be cleaned after use.•A 5 kDa ceramic membrane provided stable performance with 95% phospholipid rejection.•The membrane could be cleaned by flushing with hexane at high crossflow velocity.