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Electrochemical Reduction of alpha-Diketones and alpha-Diimines in the Presence of a Bielectrophilic Substrate: Synthesis of New Aza-Crown Compounds
Journal article   Peer reviewed

Electrochemical Reduction of alpha-Diketones and alpha-Diimines in the Presence of a Bielectrophilic Substrate: Synthesis of New Aza-Crown Compounds

Hayet Khemis Medini, Nejib Hussein Mekni, Sami Ben Aoun and Khaled Boujlel
Journal of the Electrochemical Society, Vol.164(2), pp.G36-G43
01/01/2017
DOI: https://doi.org/10.1149/2.0871702jes

Abstract

Electrochemistry Materials Science Materials Science, Coatings & Films Physical Sciences Science & Technology Technology
The electrochemical reduction of alpha-diketones and alpha-diimines with the tritosylate of diethanolamine produces the corresponding aza crown compounds. This study was conducted using cyclic voltammetry in an aprotic medium and by preparative electrolysis on a stirred mercury pool. The obtained products were fully characterized by spectroscopic IR, NMR and HRMS methods and by elementary analysis. (C) 2016 The Electrochemical Society.

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