Abstract
Cobalt-titanium carbide nanoparticles (Co-TiC NPs) embedded on carbon nanofibers (composite) were prepared by electrospinning of a solution containing cobalt acetate tetrahydrate (CoAc), titanium (IV) isopropoxide (TIIP) and polyvinylpyrrolidone (PVP) in acetic acid and ethanol. It was then subjected to a carbonation process at a low temperature (850 °C) since the composite contains metal carbide. The obtained composite, as an efficient electrode, was used as an alternative to Pt-free counter electrode (CE) for fuel cells (FCs) and dye-sensitized solar cells (DSSCs). Cyclic voltammetry (CV) and chronoamperatory (CA) tests were used to measure the composite electrode's performance in methanol oxidation. The results showed that the introduced composite could enhance both methanol electro-oxidation and electrochemical stability as the low onset potential and high current density of the composite electrode were obtained at 189 mV and ∼90 mA cm−2 vs. Ag/AgCl, respectively. The composite also was examined in dye-sensitized solar cells as counter electrode (CE). The results showed that the composite electrode was effective, providing stable electrocatalytic activity (ECA) and conductivity, indicating the composite can improve catalytic activity in triiodide reduction. The short-circuit current density (Jsc), open circuit voltage (VOC), fill factor (FF), and energy conversion efficiency (η) were found to be ∼9.98 mA cm−2, 0.758 V, 0.507 and 3.87%, respectively. The high ECA could be attributed to the synergic effects from all the pristine components.
Cyclic voltammograms for activation the introduced NFs. [Display omitted]
•Co-TiC NPs incorporated inside carbon NFs are introduced.•Co-TiC NPs@carbon NFs were synthesized by simple and effective technique.•Co enhances the formation of TiC at low temperature.•Due to carbon shelling, the introduced composite are chemically stable.•Composite showed good electrochemical activity in the methanol fuel cells and DSSCs.