Abstract
In this work, single crystalline alpha-Fe2O3 nanoflakes (NFs) are formed in a highly dense array by Au seeding of a Fe substrate by a thermal oxidation technique. The NFs are conformally decorated with a thin FeOOH cocatalyst layer. Photoelectrochemical (PEC) measurements show that this photoanode, incorporating alpha-Fe2O3/ FeOOH NFs rooted on the Au/Fe structure, exhibits significantly enhanced PEC water oxidation performance compared to the plain alpha-Fe2O3 nanostructure on the Fe substrate. The a-Fe2O3/ FeOOH NFs on Au/Fe photoanode yields a photocurrent density of 3.1 mA cm(-2) a remarkably low onset potential of 0.5- 0.6 V-RHE in 1m KOH under AM 1.5G (00 mWcm(-2)) simulated sunlight illumination. The enhancement in PEC performance can be attributed to a synergistic effect of the FeOOH top decoration and the Au underlayer, whereby FeOOH facilitates hole transfer at the interface of electrode/electrolyte and the Au layer provides a sink for the electron transport to the back contact. This results in a drastically improved charge-separation efficiency in the single crystalline alpha-Fe2O3 NF photoanode.