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Entropy-driven helical mesostructure formation with achiral cationic surfactant templates
Journal article   Peer reviewed

Entropy-driven helical mesostructure formation with achiral cationic surfactant templates

Yu Han, Lan Zhao and Jackie Y. Ying
Advanced materials (Weinheim), Vol.19(18), pp.2454-2459
17/09/2007

Abstract

Chemistry Chemistry, Multidisciplinary Chemistry, Physical Materials Science Materials Science, Multidisciplinary Nanoscience & Nanotechnology Physical Sciences Physics Physics, Applied Physics, Condensed Matter Science & Technology Science & Technology - Other Topics Technology
Helical mesoporous silica is synthesized using achiral cationic surfactants as template in a highly concentrated ammonia solution. The particle morphology and the helical pitch of this material could be systematically controlled by simply varying the ammonia concentration (see figure). The helical mesoporous silica was characterized by transmission electron microscopy tomography for the first time.

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