Abstract
•Portland cement mortar amended with date palm ash.•Direct impact assessment found no concern of pollutants exceeding the regulatory thresholds.•No pollutants exceeded the toxicity characteristic limits.•Aluminum exceeded the regulatory threshold when the date palm ash amended with mortar in encapsulated form.•While concentration of aluminum above the regulatory threshold, it experiences low mobility to the environment.
Saudi Arabia’s date palm industry generates date palm ash (DPA) from the thermal processing of palm oil fibers and shells. This waste material has potential to be used as partial replacement of cement in structural mortar. However, no studies to date have examined its pollution potential. DPA was used as a cement replacement in Portland cement mortar (PCM) using a 10% and 100% replacement rate and then compared to an ordinary PCM control sample. Total elemental analysis, the toxicity characteristic leaching procedure (TCLP) and monolith leaching tests were conducted. Elemental analysis revealed a standard elemental profile similar to data for the comparably used wood ash. Aluminum (Al) and iron (Fe) were elements with the greatest abundance in DPA but no element exceeded regulatory thresholds. Leachability testing revealed that while concentrations of Al and Fe may appear high in DPA, they experience relatively low mobility when encapsulated in PCM matrices as indicated by their calculated leachability index. The results presented in this paper indicate that DPA poses no environmental risk to human health when used as cement replacement in PCM.