Abstract
The inhibition effect of new isomers of the triazole derivative family, namely 1-[(4-ethyl-2-phenyl-4,5-dihydro-1,3-oxazol-4-yl)methyl]-4-phenyl-1H-1,2,3 -triazole (Ph4) and 1-[(4-ethy1-2-phenyl-4,5-dihydro-1,3-oxazol-4-yl)methyl]-5-phenyl-1H-1,2,3-triazole (Ph5), on mild steel corrosion in 1 M HCl was synthesized and evaluated using weight loss, electrochemical polarization, and impedance spectroscopy. The Ph4 compound was the best rust inhibitor and its inhibitory efficiency increased with increasing concentration, reaching 95% at 10(-3) M. The polarization curves indicated that Ph4 and Ph5 are mixed-type inhibitors. EIS diagram appears a single capacitive loop, where diameter increases gradually as the inhibitors concentration. The change in the substitution phenyl from position 5(Ph5) to position 4 (Ph4) in the triazole ring increased the inhibitory effect of the triazole compounds. The effect of temperature on the corrosion behavior of mild steel indicated that the inhibitory efficiency of both inhibitors decreased with increasing temperature in the range308-338K. The DFT study correlated well with the experimental results.