Abstract
A series of air‐stable nickel complexes containing triazine‐based PN3P‐pincer ligands were synthesized and fully characterized. Complex 3 contains a de‐aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post‐modification strategy, the Me‐PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P‐pincer nickel complexes.
A series of air‐stable nickel complexes containing triazine‐based PN3‐pincer ligands were synthesized and fully characterized. With a post‐modification strategy, the de‐aromatized Me‐PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P‐pincer nickel complexes.