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Extending the coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) to cobalt centers: First examples of Co-PTA complexes and of a metal complex with the PTA oxide ligand
Journal article   Peer reviewed

Extending the coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) to cobalt centers: First examples of Co-PTA complexes and of a metal complex with the PTA oxide ligand

Lukasz Jaremko, Alexander M. Kirillov, Piotr Smolenski, Tadeusz Lis and Armando J. L. Pombeiro
Inorganic chemistry, Vol.47(8), pp.2922-2924
21/04/2008
DOI: https://doi.org/10.1021/ic702373b
PMID: 18345600

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
Water-soluble Co-III and Co-II complexes with P- or N-coordinated PTA or PTA oxide ligands, respectively, have been prepared and fully characterized, constituting the first examples of cobalt compounds bearing PTA or any ligand with a cage-like PTA core, the latter complex providing also the first PTA oxide coordination to a metal center.

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