Abstract
Composites of polybenzimidazole (PBI) with proton-exchanged AMH-3 and swollen AMH-3 were prepared, characterized by electron microscopy and X-ray scattering and tested for hydrogen/carbon dioxide ideal selectivity. Proton-exchanged AMH-3 was prepared under mild conditions by the ion exchange of Sr and Na cations in the original AMH-3 using aqueous solution of
dl-histidine. Swollen AMH-3 was prepared by sequential intercalation of dodecylamine following the ion exchange in the presence of
dl-histidine. Both silicate materials were introduced into a continuous phase of PBI as a selective phase. Mixed matrix nanocomposite membranes, prepared under certain casting conditions, with only 3
wt% of swollen AMH-3 present substantial increase of hydrogen/carbon dioxide ideal selectivity at 35
°C, i.e., more than by a factor of 2 compared to pure PBI membranes (40 vs. 15). Similar ideal selectivity was observed using higher loadings (e.g., 14%) of proton-exchanged AMH-3 particles suggesting that transport of hydrogen is faster than carbon dioxide in AMH-3-derived silicates. However, the ideal selectivity of mixed matrix membranes approaches that of pure polymer as the operating temperature increases to 100
°C and 200
°C. The composite membranes with AMH-3-derived materials were compared with MCM-22/PBI membranes. Composite membranes incorporating MCM-22 plate-like crystals show no selectivity enhancements possibly due to the presence of larger pores in MCM-22.