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Formation and stability of 3-5 atom gold clusters from gold complexes during the catalytic reaction: dependence on ligands and counteranions
Journal article   Peer reviewed

Formation and stability of 3-5 atom gold clusters from gold complexes during the catalytic reaction: dependence on ligands and counteranions

Judit Oliver-Meseguer, Antonio Leyva-Perez, Saud I. Al-Resayes and Avelino Corma
Chemical communications (Cambridge, England), Vol.49(71), pp.7782-7784
14/09/2013
DOI: https://doi.org/10.1039/c3cc44104k
PMID: 23900257

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Gold complexes and salts decompose to catalytically active 3-5 atom gold clusters during the one-pot acylation-hydration of propargyl alcohols. Kinetic and spectroscopic studies show that released ligands and counteranions exert a direct effect on the formation and stability of the clusters.

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