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From ruthenium olefin metathesis catalyst to (eta(5)-3-phenylindenyl)hydrido complex via alcoholysis
Journal article   Peer reviewed

From ruthenium olefin metathesis catalyst to (eta(5)-3-phenylindenyl)hydrido complex via alcoholysis

Simone Manzini, David J. Nelson, Tomas Lebl, Albert Poater, Luigi Cavallo, Alexandra M. Z. Slawin and Steven P. Nolan
Chemical communications (Cambridge, England), Vol.50(17), pp.2205-2207
10/01/2014
DOI: https://doi.org/10.1039/c3cc49481k
PMID: 24435451

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
The synthesis and characterisation of [Ru(H)(eta(5)-3-phenylindenyl)-( Bu-i-Phoban)(2)] 4 is reported (Bu-i-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M-11, in a process that was previously thought to be limited to analogous complex [RuCl2(PPh3)(2)(3-phenylindenylidene)] (M-10).

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