Abstract
Corrosion inhibition performance of an environmentally benign compound, gelatin on X60 steel in 15% hydrochloric acid (HCl) at 25 °C, which simulate oil well acidizing environment was investigated in this study. The inhibition efficiency of the gelatin was examined using weight loss, potentiodynamic polarization (PDP), linear polarization (LPR), and electrochemical impedance spectroscopy (EIS) measurements techniques. Both the weight loss and the electrochemical results showed that the gelatin exhibits high inhibition efficiency and the inhibition efficiency increases with increasing gelatin concentration. The addition of low concentration of potassium iodide improves the inhibition efficiency of gelatin considerably. The ATR-FTIR and SEM/EDX surface morphology analyses provide evidence of formation of protective gelatin film on the metal surface. The gelatin molecules are predicted to adsorb on the metal surface through an interaction between the nitrogen and oxygen atoms of gelatin and the metal surface to form a metal/gelatin complex on the metal surface.
•Gelatin can be utilized as green corrosion inhibitor for oil well acidizing.•Gelatin exhibits good inhibition efficiency which was further improved with iodide ions addition.•SEM-EDX and FT-IR analysis confirmed formation of protective gelatin film on steel surface.•The gelatin molecules adsorb on the metal surface via the amide groups.