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Geometric requirements and examples of important structures in the assembly of square building blocks
Journal article   Peer reviewed

Geometric requirements and examples of important structures in the assembly of square building blocks

Mohamed Eddaoudi, Jaheon Kim, David Vodak, Andrea Sudik, Joseph Wachter, Michael O'Keeffe and Omar M Yaghi
Proceedings of the National Academy of Sciences - PNAS, Vol.99(8), pp.4900-4904
16/04/2002
PMCID: PMC122691
PMID: 11959942

Abstract

Chemistry - methods Crystallography, X-Ray - methods Macromolecular Substances Models, Chemical Models, Molecular X-Ray Diffraction - methods
The basic structures for linking squares into polyhedra and networks (reticulation) are enumerated, and corresponding examples are described in which crystals were synthesized by linking paddle wheel (square) units into metal-organic frameworks (MOFs)--named MOF-102 to MOF-112.

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