Abstract
Groundwater quality is a critical issue in arid and semiarid countries, where it is one of the most reliable sources of water on which people depend. Water quality is a vital concern in the Kingdom of Saudi Arabia as it affects the health of its people, the growth of its agriculture, and its economic development. In this study, the objectives were to: (1) investigate the depletion rate of groundwater storage (GWS) in the study area by using Gravity Recovery and Climate Experiment (GRACE) data from April 2002 to April 2016 to quantify terrestrial water storage; (2) determine the ionic composition of cations and anions for 24 samples (12 samples from Arabian Shield and 12 from Arabian Shelf in Saudi Arabia); and (3) assess the water quality of the aquifer. The results show a GRACE-derived GWS depletion of - 2 +/- 0.13 km(3)/year. Ionic compositions reveal two main groups: group I, with well depths of 144-607 m, and group II, with well depths of 12-150 m. Group I waters (all from the Saq aquifer) appear to be fossil waters, while group II waters (alluvial aquifer) appear to be mixed waters. As illustrated by the use of a Piper diagram, 85% of the samples in Arabian Shelf are characterized as a mixed water of calcium, magnesium, chloride, and sulfate (SO4). In the Arabian Shield, 50% of the samples are characterized as Ca-Cl waters. Since most of the samples (98%) are from domestic wells used for drinking water and have the potential for radioactivity in the groundwater, it is essential to complete radioactive analysis and confirm acceptable water quality, based on the standards of the Water Health Organization and the Saudi Arabian Standards Organization.