Heterometallic molecular complex [Co2Gd(NO3)(piv)(6)(py)(2)] and coordination polymer [{CoGd(dma)(2)}(2)(bdc)(5)]center dot 4DMA: the synthesis, structure, and properties

A. A. Sapianik; I. A. Lutsenko; M. A. Kiskin; A. A. Sidorov; I. L. Eremenko; D. G. Samsonenko; D. N. Dybtsev; V. P. Fedin

doi:10.1007/s11172-016-1624-4

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Heterometallic molecular complex [Co2Gd(NO3)(piv)(6)(py)(2)] and coordination polymer [{CoGd(dma)(2)}(2)(bdc)(5)]center dot 4DMA: the synthesis, structure, and properties

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Heterometallic molecular complex [Co2Gd(NO3)(piv)(6)(py)(2)] and coordination polymer [{CoGd(dma)(2)}(2)(bdc)(5)]center dot 4DMA: the synthesis, structure, and properties

A. A. Sapianik, I. A. Lutsenko, M. A. Kiskin, A. A. Sidorov, I. L. Eremenko, D. G. Samsonenko, D. N. Dybtsev and V. P. Fedin

Russian chemical bulletin, Vol.65(11), pp.2601-2606

01/11/2016

DOI: https://doi.org/10.1007/s11172-016-1624-4

Abstract

Chemistry

Chemistry, Multidisciplinary

Physical Sciences

Science & Technology

A new heterometallic molecular complex [Co2Gd(NO3)(piv)(6)(py)(2)] (1, piv = (-O2CBut), py = pyridine) was synthesized. Its reaction with terephthalic acid (H(2)bdc) in N,N-dimethylacetamide (DMA) results in metal-organic coordination polymer [{CoGd(dma)(2)}(2)(bdc)(5)]center dot 4DMA (2). The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis. The structure of 2 has two types of channels (4x8 and 5x16 ) that are occupied by coordinated and guest DMA molecules.

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Title: Heterometallic molecular complex [Co2Gd(NO3)(piv)(6)(py)(2)] and coordination polymer [{CoGd(dma)(2)}(2)(bdc)(5)]center dot 4DMA: the synthesis, structure, and properties
Creators - without role: A. A. Sapianik - Nikolaev Institute of Inorganic Chemistry
I. A. Lutsenko - NS Kurnakova Institute of General and Inorganic Chemistry
M. A. Kiskin - NS Kurnakova Institute of General and Inorganic Chemistry
A. A. Sidorov - NS Kurnakova Institute of General and Inorganic Chemistry
I. L. Eremenko - NS Kurnakova Institute of General and Inorganic Chemistry
D. G. Samsonenko - Novosibirsk State University
D. N. Dybtsev - Nikolaev Institute of Inorganic Chemistry
V. P. Fedin - Nikolaev Institute of Inorganic Chemistry
Publication Details: Russian chemical bulletin, Vol.65(11), pp.2601-2606
Publisher: Springer Nature
Number of pages: 6
Grant note: 14-23-00176 / Russian Science Foundation; Russian Science Foundation (RSF) 14.Z50.31.0006 / Ministry of Education and Science of the Russian Federation; Ministry of Education and Science, Russian Federation
Identifiers: 9942051608331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article