Abstract
Hierarchical nanocomposites, which integrate electroactive materials into carbonaceous species, are significant in addressing the structural stability and electrical conductivity of electrode materials in post-lithium-ion batteries. Herein, a hierarchical nanocapsule that encapsulates Cu-doped MoS2 (Cu-MoS2) nanopetals with inner added skeletons in an organic-carbon-rich nanotube of hydrogen-substituted graphdiyne (HsGDY) has been developed for rechargeable magnesium batteries (RMB). Notably, both the incorporation of Cu in MoS2 and the generation of the inner added nanoboxes are developed from a dual-template of Cu-cysteine@HsGDY hybrid nanowire; the synthesis involves two morphology/composition evolutions by CuS@HsGDY intermediates both taking place sequentially in one continuous process. These Cu-doped MoS2 nanopetals with stress-release skeletons provide abundant active sites for Mg2+ storage. The microporous HsGDY enveloped with an extended π-conjugation system offers more effective electron and ion transfer channels. These advantages work together to make this nanocapsule an effective cathode material for RMB with a large reversible capacity and superior rate and cycling performance.