Abstract
Copper thiocyanate (CuSCN) is introduced as a hole‐injection/hole‐transport layer (HIL/HTL) for solution‐processed organic light‐emitting diodes (OLEDs). The OLED devices reported here with CuSCN as HIL/HTL perform significantly better than equivalent devices fabricated with a PEDOT:PSS HIL/HTL, and solution‐processed, phosphorescent, small‐molecule, green OLEDs with maximum luminance ≥10 000 cd m‐2, maximum luminous efficiency ≤50 cd A‐1, and maximum luminous power efficiency ≤55 lm W‐1 are demonstrated.