Highly dispersed Rh/Ce0.75Zr0.25O2-delta-eta-Al2O3/FeCrAl wire mesh catalyst for autothermal n-hexadecane reforming

T. B. Shoynkhorova; V. N. Rogozhnikov; P. A. Simonov; P. V. Snytnikov; A. N. Salanov; A. V. Kulikov; E. Y. Gerasimov; V. D. Belyaev; D. I. Potemkin; V. A. Sobyanin

doi:10.1016/j.matlet.2017.12.017

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Highly dispersed Rh/Ce0.75Zr0.25O2-delta-eta-Al2O3/FeCrAl wire mesh catalyst for autothermal n-hexadecane reforming

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Highly dispersed Rh/Ce0.75Zr0.25O2-delta-eta-Al2O3/FeCrAl wire mesh catalyst for autothermal n-hexadecane reforming

T. B. Shoynkhorova, V. N. Rogozhnikov, P. A. Simonov, P. V. Snytnikov, A. N. Salanov, A. V. Kulikov, E. Y. Gerasimov, V. D. Belyaev, D. I. Potemkin and V. A. Sobyanin

Materials letters, Vol.214, pp.290-292

01/03/2018

DOI: https://doi.org/10.1016/j.matlet.2017.12.017

Abstract

Materials Science

Materials Science, Multidisciplinary

Physical Sciences

Physics

Physics, Applied

Science & Technology

Technology

Highly dispersed Rh particles supported on Ce0.75Zr0.25O2-delta mixed with alumina were prepared by sorption-hydrolytic deposition technique. Produced catalyst exhibited high activity in autothermal reforming of n-hexadecane, but suffered from coking. Structured Rh/Ce0.75Zr0.25O2-delta-eta-Al2O3/FeCrAl catalyst was prepared by strongly bound catalytic coating deposition onto metallic wire mesh to provide effective heat transfer and avoid coking. Rh/Ce0.75Zr0.25O2-delta-eta-Al2O3/FeCrAl showed excellent performance in n-hexadecane autothermal reforming providing 100% conversion and stable operation for at least 12 h on stream without detection of any carbon deposits. (C) 2017 Elsevier B.V. All rights reserved.

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Title: Highly dispersed Rh/Ce0.75Zr0.25O2-delta-eta-Al2O3/FeCrAl wire mesh catalyst for autothermal n-hexadecane reforming
Creators - without role: T. B. Shoynkhorova - Boreskov Institute of Catalysis
V. N. Rogozhnikov - Boreskov Institute of Catalysis
P. A. Simonov - Boreskov Institute of Catalysis
P. V. Snytnikov - Boreskov Institute of Catalysis
A. N. Salanov - Boreskov Institute of Catalysis
A. V. Kulikov - Boreskov Institute of Catalysis
E. Y. Gerasimov - Boreskov Institute of Catalysis
V. D. Belyaev - Boreskov Institute of Catalysis
D. I. Potemkin - Boreskov Institute of Catalysis
V. A. Sobyanin - Boreskov Institute of Catalysis
Publication Details: Materials letters, Vol.214, pp.290-292
Publisher: Elsevier
Number of pages: 3
Grant note: 14.607.21.0149; RFMEFI60716X0149 / Ministry of Education and Science of Russian Federation; Ministry of Education and Science, Russian Federation
Identifiers: 9941750808331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article