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Highly porous and robust ionic MOFs with nia topology constructed by connecting an octahedral ligand and a trigonal prismatic metal cluster
Journal article   Peer reviewed

Highly porous and robust ionic MOFs with nia topology constructed by connecting an octahedral ligand and a trigonal prismatic metal cluster

Jiangtao Jia, Fuxing Sun, Tsolmon Borjigin, Hao Ren, Tingting Zhang, Zheng Bian, Lianxun Gao and Guangshan Zhu
Chemical communications (Cambridge, England), Vol.48(48), pp.6010-6012
01/01/2012
DOI: https://doi.org/10.1039/c2cc32347h
PMID: 22576860

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Two non-interpenetrated and isomorphous MOFs with nia topology, cationic JUC-101 and anionic JUC-102, are synthesized by connecting a trigonal prismatic metal cluster with an octahedral organic ligand. JUC-101 obtains a BET surface area of 3742 m(2) g(-1) and can absorb 4.18 wt% of H-2 at 30 atm and 77 K, while JUC-102 can absorb cationic dye molecules and release them under the triggering of ions.

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