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Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes
Journal article   Peer reviewed

Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes

Kuo-Wei Huang and Robert M Waymouth
Dalton transactions : an international journal of inorganic chemistry, Vol.4(3), pp.354-356
07/02/2004
DOI: https://doi.org/10.1039/b314027j
PMID: 15252536

Abstract

Cyclic N-Oxides - chemistry Cyclopentanes - chemistry Hydrolysis Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Titanium - chemistry
The eta1-hydroxylamido half-titanocene complex, CpTiCl2(TEMPO) 1, hydrolyzes extremely efficiently to generate (CpTiClO)4 and the protonated hydroxylamine. The efficient hydrolysis chemistry provides selective syntheses of CpTi dialkoxide and diaryloxide complexes.

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