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Hydroperoxides and aryl diazonium salts as reagents for the functionalization of non-activated olefins
Journal article   Peer reviewed

Hydroperoxides and aryl diazonium salts as reagents for the functionalization of non-activated olefins

Olga Blank, Nicole Raschke and Markus R. Heinrich
Tetrahedron letters, Vol.51(13), pp.1758-1760
31/03/2010
DOI: https://doi.org/10.1016/j.tetlet.2010.01.098

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
Hydroperoxides, olefins, and arenediazonium salts selectively combine to give azo compounds via an iron(II)-mediated three-component reaction. Starting with a fragmentation liberating acetic acid, the hydro-peroxides act as radical source and the diazonium ions as nitrogen-centered radical scavengers. (C) 2010 Elsevier Ltd. All rights reserved.

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