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Immobilization of a molecular cobalt electrocatalyst by hydrophobic interaction with a hematite photoanode for highly stable oxygen evolution
Journal article   Peer reviewed

Immobilization of a molecular cobalt electrocatalyst by hydrophobic interaction with a hematite photoanode for highly stable oxygen evolution

Khurram S. Joya, Natalia Morlanes, Edward Maloney, Valentin Rodionov and Kazuhiro Takanabe
Chemical communications (Cambridge, England), Vol.51(70), pp.13481-13484
11/09/2015
DOI: https://doi.org/10.1039/c5cc05681k
PMID: 26214272

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
A unique modification of a hematite photoanode with perfluorinated Co-phthalocyanine (CoFPc) by strong binding associated with hydrophobic interaction is demonstrated. The resultant molecular electrocatalyst - a hematite photoanode hybridmaterial showed a significant onset shift and high stability for the photoelectrochemical oxidation evolution reaction (OER).

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