Abstract
In the present study, we have analyzed the fabrication of transparent conductive Erbium (Er) co-doped CdO:Zn films by nebulizer spray method (NSP) by adding different Er level from 0 to 1.5 wt%. X-ray diffraction (XRD) pattern confirmed polycrystalline behavior of prepared Er co-doped CdO:Zn films of cubic crystalline system. Surface roughness of the films was slightly decreased from 20 nm to 16 nm. Elemental mapping and energy dispersive analysis of X-ray (EDX) spectra confirm the existence of Cd, O, Zn and Er in 1.5 wt% Er co-doped CdO:Zn film surface. The estimated optical transmittance and band gap value enhanced from 2.62 to 2.96 eV on growing Er doping concentrations. Photoluminescence (PL) spectrum emitted one strong near-band-edge (NBE) emission at ∼ 435 nm for all the Er co-doped CdO:Zn films, signify their better optical quality. Hall Effect measurements evidenced that the Er co-doping provides enhancement on the carrier concentration and reduce the electrical resistivity. The quality factor of Er co-doped CdO:Zn film thin film was increased from 1.1 × 10−4 (Ω−1) to 11.0 × 10−4 (Ω−1) for increasing the Er doping concentration from 0 to 1.5 wt%.
AFM topograph, Tauc’s plot for energy gap evaluation, PL spectra and resistivity, carrier concentration and mobility of Er co-doped CdO:Zn thin films prepared by NSP technique. [Display omitted]
•Er co-doped CdO:Zn thin films were facilely fabricated by nebulizer spray pyrolysis technique.•X-ray diffraction study confirm monophasic cubic films fabrication.•Enhancement of energy gap was found from 2.62 to 2.96 eV by Er co-doping in CdO:Zn.•Resistivity of CdO:Zn films is changed from 9.77 × 10−3 to 7.2 × 10−4 Ωcm on Er doping.•Quality factor was increased from 1.1 × 10−4 to 11.0 × 10−4 Ω−1 on increasing of Er content.