Abstract
Research on large northern rivers suggests that as permafrost thaws, deeper groundwater flowpaths become active, resulting in greater baseflow, increased concentrations of weathering ions and reduced concentrations of dissolved organic carbon in the streamflow. In contrast, at the headwater-catchment scale, where understanding of groundwater/surface-water interactions is developed, inter-annual variability in climate and hydrology result in complex hydrological and chemical responses to change. This paper reports on a 4-year runoff investigation in an alpine discontinuous permafrost environment in Yukon, Canada, using stable isotopes, major dissolved ions and hydrometric data, to provide enhanced insight into the inter-annual-variability runoff-generation processes. Stable isotope results suggest that pre-event (old) water stored within the catchment dominates the snowmelt hydrograph, and dissolved ion results reveal that groundwater pathways occur predominantly in the near-surface during freshet. Dissolved organic carbon varies inter-annually, reflecting changing melt patterns, whereas weathering ions generated from deeper flowpaths become diluted. The total snow-water equivalent does not have a major influence on the fraction of snowmelt water reaching the stream or the runoff ratio. Results from multiple years highlight the considerable variability over short time scales, limiting our ability to detect climate-change influences on groundwater at the headwater scale. Copyright 2012 Springer-Verlag Berlin Heidelberg